Friday, November 14, 2014

CORROSION / WEEPING of METAL

CORROSION is defined as the deterioration or destruction of metals and alloys in the presence of an environment by chemical or electrochemical means.

# Also said as reaction of metal with the environmental species.

# ( IUPAC ) Is an irreversible inter-facial reaction of a material with its environment, which results in consumption or dissolution into the material of a component of the environment.


CLASSIFICATION

  • Chemical and Electrochemical
  • Wet and Dry 

TYPES OF CORROSION
  • UNIFORM CORROSION - occurs on the whole surface.
  • PITTING CORROSION - occurs in the local pits on a surface.
  • CREVICE CORROSION - occurs on the grooves when bolts are present.
  • GALVANIC CORROSION - occurs when two metals come in contact, and the reactive metal gets corroded leaving the other metal safe.
  • ENVIRONMENTAL CORROSION - occurs due to bad harsh conditions.
  • STRESS CORROSION - occurs due to severe stress causing damage to the metal.
  • FRETTING CORROSION - due to repeated wearing off of the machinery components.

FACTORS CAUSING CORROSION
  • Oxygen
  • Moisture
  • Reactivity of the metal
  • Electrolyte presence
  • Galvanization
  • Pollutants like NO2 CO2.
  • High temperature
  • Surface ( Rough or Smooth ) Nature
  • Humidity

PREVENTION FROM CORROSION
  • Electroplating - coating with another metal with help of electricity.
  • Barrier protection - with paints and enamels.
  • Rective Coating - coating with a more reactive metal which gets corroded ( Sacrificial ).
  • Anodization - Electrochemical method of depositing an inert and stable oxide layer which is more durable and decorative ( Aluminium ).
  • Cathodic Protection - A more reactive metal is attached via wire, to the underground pipelines and tanks, which by the principle of galvanization gets reduced and keeps the tanks safe.

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